[1]张培新,汪静伟,黄亮,等.锂离子电池硅基负极材料研究现状与发展趋势[J].深圳大学学报理工版,2014,31(5):441-451.[doi:10.3724/SP.J.1249.2014.05441]
　Zhang Peixin,Wang Jingwei,Huang Liang,et al.Research status and development trend on Si-based anode materials of lithium ion batteries[J].Journal of Shenzhen University Science and Engineering,2014,31(5):441-451.[doi:10.3724/SP.J.1249.2014.05441]
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锂离子电池硅基负极材料研究现状与发展趋势()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第31卷
期数:
2014年第5期
页码:
441-451
栏目:
化学与化工
出版日期:
2014-09-20

文章信息/Info

Title:
Research status and development trend on Si-based anode materials of lithium ion batteries
文章编号:
201405001
作者:
张培新1;  汪静伟1; 黄亮1; 张冬云1; 2
1）深圳大学化学与化工学院，深圳 518060
2）哈尔滨工业大学深圳研究生院，深圳 518055
Author(s):
Zhang Peixin1;  Wang Jingwei1;  Huang Liang1;  and Zhang Dongyun1;  2
1) College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060, P.R.China
2）Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, P.R.China
关键词:
应用化学; 锂离子电池; 负极材料; 硅薄膜; 硅基合金; 硅基复合材料
Keywords:
applied chemistry;  lithium ion batteries;  anode materials;  silicon film;  silicon-based alloy;  silicon-based nanocomposite materials
分类号:
O 69
DOI:
10.3724/SP.J.1249.2014.05441
文献标志码:
A
摘要:
硅基负极材料因具有高电化学容量是一种极具发展前景的锂离子电池负极材料.评述单质硅、硅-金属合金、硅-碳复合材料以及其他硅基复合材料作为锂离子二次电池负极材料的最新研究成果，分析锂离子电池硅负极材料存在问题，探讨硅基负极材料的合成、制备工艺以及未来硅基材料的研究方向和应用前景. 分析结果表明，通过硅的纳米化、无定形化、合金化及复合化等技术手段，实现硅基负极材料同时兼备高容量、长寿命、高库伦效率和倍率性能，是未来的主要发展方向.
Abstract:
The silicon-based anode materials are of great importance for lithium ion batteries (LIBs) because of their high capacity. This paper reviews the latest research achievements of the silicon, silicon-metal alloys, silicon-carbon composites and other composite materials as anodes materials and discusses their research and application prospects. It also analyzes the existing problems of pure silicon anodes and focuses mainly on the novel silicon based anode materials. Regarding future research and application, the predominant direction will be to promote both cycle performance and electrochemical performance through the comprehensive application of nanocrystallization, amorphization, alloying and compounding of silicon-based materials.

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备注/Memo

备注/Memo:
Received：2014-06-25；Accepted：2014-07-17
Foundation：National Natural Science Foundation of China (51374146); Shenzhen Science and Technology Research Foundation for Basic Project (JCYJ20120613173950029)
Corresponding author：Professor Zhang Peixin. E-mail: pxzhang@szu.edu.cn
Citation：Zhang Peixin, Wang Jingwei, Huang Liang, et al. Research status and development trend on Si-based anode materials of lithium ion batteries［J］. Journal of Shenzhen University Science and Engineering, 2014, 31(5): 441-451.（in Chinese）
基金项目：国家自然科学基金资助项目（51374146）；深圳市基础研究计划资助项目（JCYJ20120613173950029）
作者简介：张培新（1967—），男（瑶族），广西壮族自治区贵港市人，深圳大学教授、博士生导师，E-mail:pxzhang@szu.edu.cn
引文：张培新, 汪静伟，黄亮，等. 锂离子电池硅基负极材料研究现状与发展趋势［J］. 深圳大学学报理工版，2014，31（5）：441-451.
更新日期/Last Update: 2014-09-11