[1]倪卓,郭震,林煜豪,等.PA6/ABS共混材料的微观结构与相容性[J].深圳大学学报理工版,2019,36(4):398-404.[doi:10.3724/SP.J.1249.2019.04398]
　NI Zhuo,GUO Zhen,LIN Yuhao,et al.Microstructure and compatibility of PA6/ABS blends[J].Journal of Shenzhen University Science and Engineering,2019,36(4):398-404.[doi:10.3724/SP.J.1249.2019.04398]
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PA6/ABS共混材料的微观结构与相容性()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第36卷
期数:
2019年第4期
页码:
398-404
栏目:
【材料科学】
出版日期:
2019-07-10

文章信息/Info

Title:
Microstructure and compatibility of PA6/ABS blends
作者:
倪卓1; 郭震1; 林煜豪1; 姜苏俊2; 柴晓燕1
1）深圳大学化学与环境工程学院，广东深圳518060；2）广州市金发科技股份有限公司，广东广州 510020
Author(s):
NI Zhuo1;  GUO Zhen1;  LIN Yuhao1;  JIANG Sujun2;  and CHAI Xiaoyan1
1) College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, Guangdong Province, P.R.China 2) Guangzhou Blonde Technology Co., Ltd., Guangzhou 510020, Guangdong Province, P.R.China
关键词:
复合材料; 聚酰胺6; 丙烯腈-丁二烯-苯乙烯共聚物; 共混改性; 微观结构; 相容性; 反应性增容剂; 接枝反应
Keywords:
combined material;  polyamide 6;  acrylonitrile-butadiene-styrene copolymer;  blending and modif-ication;  microscopic structure;  compatibility;  reactive compatibilizer;  grafting chemical reaction
分类号:
TQ322
DOI:
10.3724/SP.J.1249.2019.04398
文献标志码:
A
摘要:
为改善PA6/ABS共混材料的微观结构与相容性，提高该共混材料的性能, 分析了尼龙6(polyamide 6, PA6)结晶行为、丙烯腈-丁二烯-苯乙烯共聚物(acrylonitrile-butad-iene-styrene copolymer, ABS) “核-壳”结构、共混物组成和工艺等条件对PA6/ABS共混材料微观结构与相容性的影响，介绍环氧型和酸酐型反应性增容剂对PA6/ABS共混材料微观结构与性能的影响及其作用机理，并对PA6/ABS共混材料的理论研究和工程应用进行评述. 分析表明，随着PA6/ABS共混材料中组分ABS含量增多，PA6的微观形貌由球晶向片晶转变，且ABS“核-壳”结构颗粒可有效增韧PA6. 反应性增容剂与PA6/ABS共混材料发生的接枝反应可降低界面张力，使分散相颗粒分布均匀.
Abstract:
Aiming at improving microstructure and compatibility of polyamide/acrylonitrile-butadiene-styrene copolymer （PA6/ABS） blend materials, and enhancing their properties, this paper investigates some influence factors on the microstructure and compatibility of the PA6/A BS blend materials, including crystallization behavior of PA6, ABS “core-shell” structure, blend composition and process. Especially, this paper reports the effect and mechanism of epoxy and anhydride types of reactive compatibilizers on the microstructure and properties of PA6/ABS blend materials. Additionally, this paper summarizes theoretical research and engineering application of PA6/ABS blends. The results show that with the increase of ABS content in PA6/ABS blend materials, the morphology of PA6 changes from spherical crystal to sheet crystal, and ABS particles with “core-shell” structure can effectively toughen PA6, The grafting chemical reaction, which occurs between reactive compatibilizers and PA6/ABS blend materials, reduces the interfacial tension and makes uniform distribution of dispersed phase particles.

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　NI Zhuo,LIU Jian-hong,WEI Bo,et al.Microstructural charaterization of Polyetheretherketon/AS4 composites[J].Journal of Shenzhen University Science and Engineering,2007,24(4):47.
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更新日期/Last Update: 2019-07-04