[1]王成云,刘彩明,林君峰,等.纺织品中紫外线吸收剂的快速筛查和确证[J].深圳大学学报理工版,2017,34(3):322-330.[doi:10.3724/SP.J.1249.2017.03322]
 Wang Chengyun,Liu Caiming,Lin Junfeng,et al.Rapid screening and confirmation of ultraviolet absorbers in textiles[J].Journal of Shenzhen University Science and Engineering,2017,34(3):322-330.[doi:10.3724/SP.J.1249.2017.03322]
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纺织品中紫外线吸收剂的快速筛查和确证()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第34卷
期数:
2017年第3期
页码:
322-330
栏目:
食品安全
出版日期:
2017-05-30

文章信息/Info

Title:
Rapid screening and confirmation of ultraviolet absorbers in textiles
文章编号:
201703016
作者:
王成云1刘彩明1林君峰1谢堂堂1沈雅雯2崔玮3
1)深圳出入境检验检疫局工业品检测技术中心,广东深圳 518067
2)深圳大学化学与环境工程学院,广东深圳 518060
3)深圳职业技术学院应用化学与生物技术学院,广东深圳 518055
Author(s):
Wang Chengyun1 Liu Caiming1 Lin Junfeng1 Xie Tangtang1 Shen Yawen2 and Cui Wei3
1) The Testing and Technology Center for Industrial Products, Shenzhen Entry-Exit Inspection and Quarantine Bureau, Shenzhen 518067, Guangdong Province, P.R.China
2) College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, Guangdong Province, P.R.China
3) School of Applied Chemistry and Biological Technology, Shenzhen Polytechnic, Shenzhen 518055, Guangdong Province, P.R.China
关键词:
分析化学超声萃取纺织品紫外线吸收剂超高效液相色谱静电场轨道阱高分辨质谱正交实验
Keywords:
analytical chemistry ultrasonic extraction textiles ultraviolet absorbers ultra-high performance liquid chromatography orbitrap high resolution mass spectrometry orthogonal experiment
分类号:
O 658
DOI:
10.3724/SP.J.1249.2017.03322
文献标志码:
A
摘要:
建立一种筛查和确证纺织品中紫外线吸收剂的超高效液相色谱/静电场轨道阱高分辨质谱(ultra-high performance liquid chromatography/orbitrap high resolution mass spectrometry, UPLC/Orbitrap HRMS)分析方法,以甲醇为萃取溶剂,超声萃取纺织品中的紫外线吸收剂,萃取液经浓缩定容后进行UPLC/Orbitrap HRMS分析,利用提取离子色谱峰面积进行外标法定量.在Hypersil Gold色谱柱(100 mm×2.1 mm, 1.9 μm)上完成19种紫外线吸收剂的色谱分离,流动相为甲醇和水,采取梯度洗脱方式.质谱分析分别采用电喷雾正负离子(ESI+和ESI-)电离模式,在质荷比m/z为100~700范围内进行1级质谱全扫描.利用保留时间和准分子离子的精确质量数进行定性,利用数据依赖扫描模式获得的离子质谱图进行定性确证,19种紫外线吸收剂的质量数准确度误差均小于2×10-6.19种紫外线吸收剂的定量限为0.01~0.50 μg/kg,在3个不同加标水平下,方法的平均加标回收率为82.35%~94.58%,相对标准偏差为3.37%~9.98%.应用该方法对市售纺织品中紫外线吸收剂进行筛查,在1个样品中检出UV-327.
Abstract:
An effective method was established for rapid screening and confirmation of ultraviolet absorbers in textiles by ultra-high performance liquid chromatography/orbitrap high resolution mass spectrometry (UPLC/Orbitrap HRMS) technique. Ultraviolet absorbers in textiles were first ultrasonically extracted using methanol as the extraction solvent. Then, the extract was concentrated and analyzed by UPLC/Orbitrap HRMS. The quantitative analysis was carried out by the peak area in extracted chromatogram, and the concentration of each analyte was calibrated by the external standard method. The chromatographic separation of nineteen ultraviolet absorbers was carried out on a Hypersil Gold column (100 mm×2.1 mm, 1.9 μm) by gradient elution of methanol and water. The mass spectrometry analysis was carried out by Orbitrap HRMS in ESI+ and ESI- modes. Full-scan experiment was carried out in the range for m/z from 100 to 700. The screening and qualitative analysis were carried out by the retention time and the accurate mass of quasi-molecular ion and nineteen ultraviolet absorbers were routinely detected with mass accuracy errors below 2×10-6. The confirmation analysis for target compounds was performed with qualitative fragments obtained by data-dependent scan mode. The limits of quantification varied from 0.01 to 0.50 μg/kg. The blank samples were spiked at three levels, and the average spiked recoveries changed from 82.35% to 94.58% with the relative standard deviation (RSD)-changing from 3.37% to 9.98%. The proposed method was applied in the rapid screening of ultraviolet absorbers in textiles available commercially and UV-327 was detected in one sample.

参考文献/References:

[1] Tsatsaroni E G, Eleftheriadis I C. UV-absorbers in the dyeing of polyester with disperse dyes[J]. Dye and Pigments, 2004, 61: 141-147.
[2] Aultz D E. The development of a polymerisablebenzotriazolestabiliser[J].Speciality Chemicals, 1996, 16(2): 71-74.
[3] Farre M L, Perez S, Kantiani, Barcelo D. Fate and toxicity of emerging pollutants, their metabolites and transformation products in the aquatic environment[J]. Trends in Analytical Chemistry, 2008, 27(11): 991-1007.
[4] Nakata H, Shinohara R I, NakazawaY,et al. Asia-Pacific mussel watch for emerging pollutants: distribution of synthetic musks and benzotriazole UV stabilizers in Asia and US coastal waters[J]. Marine Pollution Bulletin, 2012, 64(10): 2211-2218.
[5] Kim J, Isobe T, Malarvannan G, et al. Contamination of benzotriazole ultraviolet stabilizers in house dust from Philippines: implications on human exposure[J]. Science of the Total Environment, 2012, 424: 174-181.
[6] European Unlon.Commission Regulation (EU) No. 10/2011 of 14 Junuary 2011 on plastic materials and articles intended to come into contact with food:CELEX 32011R0010[R/OL]. (2001-01-15)[2016-09-15].http://eur-lex.europa.eu/legal-content/EN/ALL/?uri=CELEX:32011R0010.
[7] The International Oeko-Tex Association. Oeko-Tex Standard 100 (2016 ed.)[S/OL]. https://www.oeko-tex.com/en/business/certifications_and_services/ots_100/ots_100_limit_values/ots_100_limit_values.xhtml.
[8] 薛建平,蔡涛,赵玲. 高效液相色谱法测定纺织品中苯并三唑类光稳定剂[J]. 质量技术监督研究,2014(4): 18-20.
Xue Jianping, Cai Tao, Zhao Ling. Determination of benzotriazole light stabilizers in textiles via HPLC method[J]. Quality and Technical Supervision Research, 2014(4): 18-20.(in Chinese)
[9] 薛建平,朱峰,涂貌贞. 纺织品中的2-(2′-羟基-3′,5′-二叔丁基苯基)-苯并三唑含量的气相色谱测定[J]. 质量技术监督研究,2012(4): 6-8.
Xue Jianping, Zhu Feng, Tu Maozhen. Determination of 2-(3,5-di-tert-butyl-2- hydroxyphenyl)-2H-benzotriazole in fbbric via GC method[J]. Quality and Technical Supervision Research, 2012(4): 6-8.(in Chinese)
[10] 薛建平. GC-MS测定苯并三唑类紫外线吸收剂[J]. 印染,2013,39(6): 42-44.
Xue Jianping.Determination of benzotriazole ultraviolet absorber in textiles by GC-MS[J]. Dyeing & Finishing, 2013,39(6): 42-44.(in Chinese)
[11] 王成云,廖文忠,施钦元,等. 纺织品中7种苯并三唑类紫外线吸收剂的测定[J]. 深圳大学学报理工版,2016, 33(3): 324-330.
Wang Chengyun, Liao Wenzhong, Shi Qinyuan, et al. Determination of seven benzotriazole ultraviolet absorbers in textiles[J]. Journal of Shenzhen University Science and Engineering, 2016, 33(3): 324-330.(in Chinese)
[12] 田欣欣,朱智甲,郭华,等. HPLC-MS/MS测定纺织品中苯并三唑类化合物[J]. 印染,2014,40(6): 40-43.
Tian Xinxin, Zhu Zhijia, Guo Hua, et al. Determination of benzotriazole ultraviolet absorber in textiles by HPLC-MS/MS[J]. Dyeing & Finishing, 2014, 40(6): 40-43.(in Chinese)
[13] 王成云,林君峰,李成发,等. 塑料制品中紫外线吸收剂的快速筛查[J]. 上海塑料,2016(4): 40-47.
Wang Chengyun, Lin Junfeng, Li Chengfa, et al. Rapid screening of ultraviolet absorbers in plastic products[J]. Shanghai Plastics, 2016(4): 40-47.(in Chinese)
[14] 王成云,刘斌斌,林君峰,等. 纸和纸制品中含氯酚的快速筛查和确证[J]. 造纸科学与技术,2017, 36(1): 70-77.

Wang Chengyun, Liu Binbin, Lin Junfeng, et al. Rapid screening and conformation of chlorophenols in paper and paper products[J]. Paper Science & Technology, 2017, 36(1): 70-77.(in Chinese)
[15] 王成云,褚乃清,林君峰,等. 纺织品中苯并三唑类紫外线吸收剂的测定[J]. 棉纺织技术,2016, 44(5): 71-75.
Wang Chengyun, Chu Naiqing, Lin Junfeng, et al. Test of benzotriazole ultraviolet light absorber in textiles[J]. Cotton Textile Technology, 2016, 44(5): 71-75.(in Chinese)

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备注/Memo

备注/Memo:
Received:2016-10-09;Accepted:2017-02-20
Foundation:General Administration of Quality Supervion, Inspection and Quarantine Science and Technology Plan (2014IK163); Shenzhen Entry-Exit Inspection and Quarantine Bureau Science and Technology Plan (SZ2014212)
Corresponding author:Professor Wang Chengyun. E-mail: wangchengyun2009@126.com
Citation:Wang Chengyun, Liu Caiming, Lin Junfeng, et al. Rapid screening and confirmation of ultraviolet absorbers in textiles[J]. Journal of Shenzhen University Science and Engineering, 2017, 34(3): 322-330.(in Chinese)
基金项目:国家质检总局科研资助项目(2014IK163);深圳局科研计划资助项目(SZ2014212)
作者简介:王成云(1969—),男,深圳出入境检验检疫局工业品检测技术中心教授级高级工程师. 研究方向:轻纺产品有毒有害物质分析.E-mail: wangchengyun2009@126.com
引文:王成云,刘彩明,林君峰,等. 纺织品中紫外线吸收剂的快速筛查和确证[J]. 深圳大学学报理工版,2017,34(3):322-330.
更新日期/Last Update: 2017-04-20