[1]罗园春,朱光明,汤皎宁,等.环氧树脂及其固化剂对生物微胶囊性能的影响[J].深圳大学学报理工版,2015,32(4):371-377.[doi:10.3724/SP.J.1249.2015.04371]
　Luo Yuanchun,Zhu Guangming,Tang Jiaoning,et al.Influence of epoxy resin and its curing agent on the properties of biomicrocapsule[J].Journal of Shenzhen University Science and Engineering,2015,32(4):371-377.[doi:10.3724/SP.J.1249.2015.04371]
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环氧树脂及其固化剂对生物微胶囊性能的影响()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第32卷
期数:
2015年第4期
页码:
371-377
栏目:
材料科学
出版日期:
2015-07-16

文章信息/Info

Title:
Influence of epoxy resin and its curing agent on the properties of biomicrocapsule
文章编号:
201504006
作者:
罗园春1; 朱光明1; 汤皎宁1; 邢锋2
1） 深圳大学材料学院，深圳 518060
2） 深圳大学土木工程学院，深圳 518060
Author(s):
Luo Yuanchun1;  Zhu Guangming1;  Tang Jiaoning1;  and Xing Feng2
1) College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, P.R.China
2) College of Civil Engineering, Shenzhen University, Shenzhen 518060, P.R.China
关键词:
复合材料; 微胶囊; 环氧树脂; 固化剂; 生物相容性; 抗折强度; 断裂韧性; 弹性模量
Keywords:
composite material;  microcapsules;  epoxy resin;  curing agent;  biological compatibility;  flexural strength;  fracture toughness;  elastic modulus
分类号:
Q 93；TQ 317.3
DOI:
10.3724/SP.J.1249.2015.04371
文献标志码:
A
摘要:
以环氧树脂为壁材，制备一种含有孢子的生物微胶囊，其中环氧树脂分别用N-(β-氨乙基)-γ-氨丙基三甲氧基硅烷（KH-792）、间苯二甲胺（MXDA）和2,4,6-三（二甲胺基甲基）苯酚（DMP-30）进行固化.通过耐受性测试评价环氧树脂及其固化剂对孢子的生物相容性；通过平板菌落计数法研究微胶囊化后孢子的存活率；利用纳米压痕仪测试环氧壁材的弹性模量；通过三点弯曲测试壁材的抗折强度；利用扫描电子显微镜和光学显微镜观察环氧壁材及复合基体的断面形貌.结果表明，KH-792、MXDA、DMP-30和环氧树脂对孢子活性影响依次减小；由KH-792、MXDA和DMP-30固化的环氧树脂壁材断裂韧性依次降低，弹性模量依次增大.可知由DMP-30固化环氧树脂作壁材制备的生物微胶囊具有较高的孢子存活率和较好的力学触发性能.
Abstract:
Microcapsules containing spores were prepared by using epoxy resin as the shell material. The epoxy resin was cured with N-(amino-ethyl)-amino-propyl trimethoxy silane (KH-792), M-Xylene Diamine(MXDA) and 2,4,6-Tris (dimethylaminomethyl) phenol (DMP-30), respectively. The influence of epoxy resin and its curing agent on the biocompatibility of spores were evaluated by the tolerance test method. The survival rate of microencapsulated spores was measured with the plate colony-counting method. The elastic modulus of epoxy wall was tested by a Nanoindenter. The flexural strength of the shell material was tested by the three-point bending method. The morphology of the composite matrix and the shell cross-section were characterized by a scanning electron microscope and an optical microscope. The results show that the influences of KH-792, MXDA, DMP-30 and epoxy resin on biologic activity of spores reduce in turn. KH-792, MXDA and DMP-30 respectively as the curing agent of the epoxy wall, in turn, reduce the fracture toughness while improve the elastic modulus. Therefore, the biomicrocapsules with shell materials of epoxy cured by DMP-30 show the highest rate of spores’ survival and the best performance of mechanical trigger properties.

参考文献/References:

［1］ Chen Ping, Liu Shengping, Wang Dezhong. Epoxy resin and its application［M］. Beijing: Chemical Industry Press, 2011: 128-130.(in Chinese)
陈平, 刘胜平, 王德中. 环氧树脂及其应用［M］. 北京: 化学工业出版社，2011：128-130.
［2］ Deng Chengliang, Deng Cong, Zhao Jing, et al. Water resistance, thermal stability, and flame retardation of polypropylene composites containing a novel ammonium polyphosphate microencapsulated by UV-curable epoxy acrylate resin［J］. Polymers for Advanced Technologies, 2014, 25(8): 861-871.
［3］ Liu Chengjuan, Chen Kui, Ji Lijun, et al. Preparation of microencapsulated ammonium polyphosphate as flame retardant applied in polypropylene［J］. Acta Materiae Compositae Sinica, 2015, 32(1): 1-12.(in Chinese)
刘成娟, 陈葵, 纪利俊, 等. 聚磷酸铵-环氧树脂微胶囊及其在聚丙烯中的阻燃性能［J］. 复合材料学报, 2015, 32(1): 1-12.
［4］ Liao Leping, Zhang Wei, Xin Yi, et al. Preparation and characterization of microcapsule containing epoxy resin and its self-healing performance of anticorrosion covering material［J］. Chinese Science Bulletin, 2011,56(4/5):439-443.
［5］ Li Yuan, Gu Aijuan, Liang Guozheng. Preparation and properties of poly(urea-formaldehyde)microcapsules filled with epoxy resins［J］. Materials Chemistry & Physics, 2008, 110(3):417-425.
［6］ Liu Xiuxiu, Zhang Hairui, Wang Jixiao, et al. Preparation of epoxy microcapsule based self-healing coatings and their behavior［J］. Surface and Coatings Technology, 2012,206(23):4976-4980.
［7］ Su Junfeng, Qiu Jian, Schlangen E. Stability investigation of self-healing microcapsules containing rejuvenator for bitumen［J］. Polymer Degradation and Stability, 2013,98(6):1205-1215.
［8］ Esser-Kahn A P, Odom S A, Sottos N R, et al. Triggered release from polymer capsules［J］. Macromolecules, 2011,44(14):5539-5553.
［9］ He Yongxing, Zhu Guangming, Zhou Yuming, et al. Preparation of microcapsule with Chlorine ion triggered by solvent evaporation technique［J］. Journal of Functional Materials, 2015, 24(2): 2144-2152.(in Chinese)
何永兴, 朱光明, 周玉明, 等. 溶剂蒸发法制备氯离子触发型微胶囊［J］. 功能材料, 2015, 24(2): 2144-2152.
［10］ White S R, Sottos N R, Geubelle P H, et al. Autonomic healing of polymer composites［J］. Letters to Nature, 2001,409(6822):794-797.
［11］ Tan Jiading, Cheng Jue, Guo Jing, et al. Effect of amine curing agents on curing behavior of epoxy resin and properties of cured compounds［J］. Journal of Chemical Industry and Engineering, 2011, 62(6): 1723-1729.(in Chinese)
谭家顶, 程珏, 郭晶, 等. 几种胺类固化剂对环氧树脂固化行为及固化物性能的影响［J］. 化工学报, 2011, 62(6): 1723-1729.
［12］ Wu Wei, Liu Mingchang, Chen Yu, et al. Shifting of the curing kinetics of E-51 epoxy resin［J］. Acta Materiae Compositae Sinica, 2011, 28(4): 1-6.(in Chinese)
吴唯, 刘明昌, 陈玉, 等. E-51环氧树脂固化反应中动力学转变［J］. 复合材料学报, 2011, 28(4): 1-6.
［13］ Zhang Baohua, Ye Jundan, Chen Bin, et al. Influence of curing temperature on performance of epoxy thermosets［J］. China Plastics Industry, 2009, 37(9): 66-69.(in Chinese)
张宝华, 叶俊丹, 陈斌, 等. 固化温度对环氧树脂固化物性能的影响［J］. 塑料工业, 2009, 37(9): 66-69.
［14］ Nie Ximing, Wang Zhaozeng, An Yuncheng, et al. Synthesis and properties of epoxy resin rapid curing agent at low temperature［J］. Engineering Plastics Application, 2011, 39(8): 21-23.(in Chinese)
聂锡铭, 王兆增, 安运成, 等. 环氧树脂低温快速固化剂的合成及性能研究［J］. 工程塑料应用, 2011, 39(8): 21-23.
［15］ Zhu Zhichen, Wang Qiang, Jia Qingzhu, et al. Structure-property relationship for the pharmacological and toxicological activity of heterocyclic compounds［J］. Acta Physico-Chimica Sinica, 2014, 30(6): 1086-1090.(in Chinese)
朱志臣, 王强, 贾青竹, 等. 多种类杂环化合物的药理和毒理活性系数构效关系［J］. 物理化学学报, 2014, 30(6): 1086-1090.

［16］ Long Caiyun, Zhu Jinhua. Toxicity of niphensamide［J］. Central South Pharmacy, 2009, 7(4): 249-252.(in Chinese)
龙彩云, 朱金华. 硝苯柳胺毒理研究［J］. 中南药学, 2009, 7(4): 249-252.
［17］ Zhang Xuan, Yang Ruili, Liu Chunhong, et al. Progress in toxicity of chiral herbicide mteolachlor［J］. Journal of Northwest A&F University Natural Science Edition, 2015, 43(1): 1-7.(in Chinese)
张璇, 杨瑞丽, 柳春红, 等. 手性除草剂异丙甲草胺毒理研究进展［J］. 西北农林科技大学学报自然科学版, 2015,43(1):1-7.
［18］ Dong Lin, Xu Jianning, Lin Fei. The research progress of epoxy propyl methacrylate toxicity［J］. Carcinogenesis, Teratogenesis & Mutagenesis, 2010, 22(2): 146-153.(in Chinese)
董琳, 许建宁, 林飞. 甲基丙烯酸环氧丙酯毒性的研究进展［J］. 癌变·畸变·突变, 2010, 22(2): 146-153.
［19］ Hu Yuming. Epoxy curing agent and additives［M］. Beijing: Chemical Industry Press, 2011: 131-132.(in Chinese)
胡玉明. 环氧固化剂及添加剂［M］. 北京: 化学工业出版社，2011: 131-132.
［20］ Manefield M, Harris L, Rice S A, et al. Inhibition of luminescence and virulence in the black tiger prawn (penaeus monodon) pathogen vibrio harveyi by intercellular signal antagonists［J］. Applied and Environmental Microbiology, 2000,66(5):2079-2084.
［20］ Zhang Liang, Li Xiaolong, Wang Ying, et al. The determination of the total number of colonies on different tipping papers［J］. Journal of Hunan University of Arts and Science, 2014, 26(4): 78-80.(in Chinese)
张亮, 李小龙, 王颖, 等. 不同卷烟接装纸中菌落总数的测定［J］. 湖南文理学院学报, 2014, 26(4): 78-80.
［22］ Oliver W C, Pharr G M. An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments［J］. Journal of Materials Research, 1992,7(6):1564-1583.

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备注/Memo

备注/Memo:
Received：2015-01-05；Accepted：2015-04-17
Foundation：Major International (Regional) Joint Research Project in the National Natural Fund(51120185002/U1301241); Science and Technology Project of Shenzhen (JCYJ20140418091413518)
Corresponding author：Associate professor Zhu Guangming．E-mail: gzhu@szu.edu.cn
Citation：Luo Yuanchun, Zhu Guangming, Tang Jiaoning, et al．Influence of epoxy resin and its curing agent on the properties of biomicrocapsule［J］. Journal of Shenzhen University Science and Engineering, 2015, 32(4): 371-377.（in Chinese）
基金项目：国家自然基金重大国际（地区）合作与交流项目资助（51120185002/U1301241）；深圳市科技计划资助项目（JCYJ20140418091413518）
作者简介：罗园春（1987—），男（汉族），江西省吉安市人，深圳大学硕士研究生. E-mail：luoyuanchun@yeah.net
引文：罗园春，朱光明，汤皎宁，等．环氧树脂及其固化剂对生物微胶囊性能的影响［J］. 深圳大学学报理工版，2015，32（4）：371-377.
更新日期/Last Update: 2015-06-30