[1]赵亮,张鸿,郑正,等.深圳市典型行业全氟化合物特征污染指纹[J].深圳大学学报理工版,2014,31(5):537-543.[doi:10.3724/SP.J.1249.2014.05537]
 Zhao Liang,Zhang Hong,Zheng Zheng,et al.Perfluorinated compounds pollution fingerprints in typical industries of Shenzhen[J].Journal of Shenzhen University Science and Engineering,2014,31(5):537-543.[doi:10.3724/SP.J.1249.2014.05537]
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深圳市典型行业全氟化合物特征污染指纹()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第31卷
期数:
2014年第5期
页码:
537-543
栏目:
环境与能源
出版日期:
2014-09-20

文章信息/Info

Title:
Perfluorinated compounds pollution fingerprints in typical industries of Shenzhen
文章编号:
201405014
作者:
赵亮1张鸿2郑正3何龙4柴之芳5沈金灿6杨波3
1)深圳大学生命科学学院,深圳 518060
2)深圳大学物理科学与技术学院,深圳 518060
3)深圳大学化学与化工学院,深圳518060
4)深圳市环境监测中心站,深圳 518049
5)中国科学院高能物理研究所,北京100049
6)深圳出入境检验检疫局食品检验检疫技术中心,深圳 518045
Author(s):
Zhao Liang1 Zhang Hong2 Zheng Zheng3 He Long4 Chai Zhifang5 Shen Jincan6 and Yang Bo3
1) College of Life Sciences, Shenzhen University, Shenzhen 518060, P.R.China
2) College of Physics Science and Technology, Shenzhen University, Shenzhen 518060, P.R.China
3) College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060, P.R.China
4) Shenzhen Environmental Monitoring Center, Shenzhen 518049, P.R.China
5) Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, P.R.China
6) Food Inspection Center of Shenzhen Entry-Exit Inspection and Quarantine Bureau, Shenzhen 518045, P.R.China
关键词:
土壤污染及防治环境污染化学全氟化合物一次排放源表层土特征污染指纹
Keywords:
soil pollution and control environmental pollution chemistry perfluorinated compounds (PFCs) primary emission sources topsoil pollution fingerprints
分类号:
X 53;X 131.3
DOI:
10.3724/SP.J.1249.2014.05537
文献标志码:
A
摘要:
为探究深圳市典型行业全氟化合物(perfluoronic compounds, PFCs)污染指纹,应用固相萃取分离富集与高效液相色谱-质谱联用相结合的方法,于2013年4月至6月对深圳市五金电镀、电子、塑胶和涂料4类行业28份靠近一次排放源表层土中14种PFCs含量进行分析.结果显示,全氟辛烷磺酸(perfluorooctane sulfonate, PFOS)是五金电镀行业PFCs排放的特征污染指纹, 电子行业为PFOS与全氟辛酸(perfluorooctane acid,PFOA),而塑胶和涂料行业为PFOS、PFOA以及长链PFCs;表层土PFCs总量呈五金电镀>>电子>塑胶>涂料>>城市背景的分布规律.其中,五金电镀和电子业排放的PFCs呈中链>>长链>短链的分布规律, 塑胶和涂料则呈中链>长链>>短链的分布.该结果可为环境监测与污染治理提供科学依据.
Abstract:
In order to explore the perfluorinated compounds (PFCs) pollution fingerprints of typical industries in Shenzhen, high performance liquid chromatography-tandem mass spectrometry was combined with solid phase extraction enrichment to analyze the contents of 14 PFCs species in 28 topsoil samples collected from primary emission sources of metal electroplating, electronics, plastics and coatings in Shenzhen. The results show that perfluorooctane sulfonate (PFOS) is the characteristic PFCs pollution fingerprints of metal electroplating, and PFOS and perfluorooctane acid (PFOA) are those of electronics. PFOS, PFOA as well as long-chain PFCs are those of plastics and coatings. Total PFCs in topsoil rank in the order of metal electroplating >> electronics > plastics > coatings >> the urban background. The PFCs distribution order is medium- >> long-> short-chain PFCs for electroplating and electronics, and medium-> long- >> short-chain PFCs for plastics and coatings. The results can provide scientific bases for environmental monitoring and pollution control.

参考文献/References:

[1] Prevedouros K, Cousins I T, Buck R C, et al. Sources,fate and transport of perfluorocarboxylates[J]. Environmental Science and Technology, 2006, 40(1) : 32-44.
[2] Paul A G, Jones K C, Sweetman A J. A first global production,emission, and environmental inventory for perfluorooctane sulfonate[J]. Environmental Science and Technology, 2009, 43(2): 386-392.
[3] Wang Tieyu, Lu Yonglong, Chen Chunli, et al. Perfluorinated compounds in a coastal industrial area of Tianjin, China[J]. Environmental Geochemistry and Health, 2012, 34(3):301-311.
[4] Wang P, Wang T, Giesy J P, et al. Perfluorinated compounds in soils from Liaodong Bay with concentrated fluorine industry parks in China[J]. Chemosphere, 2013, 91(6):751-757.
[5] Zhao L, McCausland P K, Folsom P W, et al. 6∶2 Fluorotelomer alcohol aerobic biotransformation in activated sludge from two domestic wastewater treatment plants[J]. Chemosphere, 2013, 92(4):464-470.
[6] Zhang Hong,Zhao Liang,He Long, et al. Pollution fingerprints and sources of perfluorinated compounds in surface soil of different functional areas[J]. Environmental Science, 2014, 35(7):2698-2704.(in Chinese)
张鸿,赵亮,何龙,等. 不同功能区表层土中全氟化合物污染指纹及其来源解析[J]. 环境科学, 2014, 35(7):2698-2704.
[7] Chen Qingwu,Zhang Hong,Chai Zhifang, et al. Residue characteristics and distributions of perfluorinated compounds in surface seawater along Shenzhen coastline[J]. Environmental Science, 2012, 33(6):1795-1800.(in Chinese)
陈清武,张鸿,柴之芳,等. 深圳市沿岸表层海水中全氟化合物的残留特征及其分布规律[J]. 环境科学, 2012, 33(6):1795-1800.
[8] HJ/T 166-2004 Monitoring technical specifications of soil environmental[S].(in Chinese)
HJ/T 166-2004土壤环境监测技术规范[S].
[9] Huang Chenghua, Li Xunsheng, Jin Guangquan. Competitive strength and market analysis of electronic chemicals and special gas containing fluorine[J]. Chemical Production and Technology, 2010, 17(6):15-18.(in Chinese)
黄澄华, 李训生, 金广泉. 电解氟化及其下游精细氟化工产品[J]. 化工生产与技术, 2010, 17(6):15-18.
[10] Mei Shengfang. Production, application and standard of PFOS and PFOA in home and abroad of China[J]. Organo-Fluorine Industry, 2008, 1(1):21-25.(in Chinese)
梅胜放.我国PFOS/PFOA的生产、应用以及国内外标准现状[J].有机氟工业, 2008, 1(1):21-25.
[11] He Na, Zhou Meng, Wang Lei, et al. Biodegradation of 6-2 fluorotelomer alcohol in activated sludge[J]. Acta Scientiae Circumstantiae, 2013, 33(2):383-388.(in Chinese)
何娜, 周萌, 汪磊, 等. 6-2氟调醇在活性污泥中的降解[J]. 环境科学学报, 2013, 33(2):383-388.
[12] D’eon J C, Hurley M D, Wallington T J, et al. Atmospheric chemistry of N-methyl perfluorobutane sulfonamidoethanol, C4F9SO2N(CH3)CH2CH2OH: kinetics and mechanism of reaction with OH[J]. Environmental Science and Technology, 2006, 40(6): 1862-1868.
[13] Rhoads K R, Janssen E M L, Luthy R G, et al. Aerobic biotransformation and fate of N-ethyl perfluorooctane sulfonamidoethanol (N-EtFOSE) in activated sludge[J]. Environmental Science and Technology, 2008, 42(8): 2873-2878.
[14] Chen Jing, Zhang Pengyi, Liu Jian. Photodegradation of perfluorinated carboxylic acids by 185 nm VUV light[J]. Environmental Science, 2007, 28(4):772-776.(in Chinese)
陈静,张彭义,刘剑. 全氟羧酸在185 nm 真空紫外光下的降解研究[J].环境科学,2007,28(4) : 772-776.
[15] Wang N, Szostek B, Buck R C,et al. Fluorotelomer alcohol biodegradation direct evidence that perfluorinated carbon chains breakdown[J]. Environmental Science and Technology, 2005,39(19) : 7516-7528.
[16] Pistocchi A,Loos R. A map of european emissions and concentrations of PFOS and PFOA[J]. Environmental Science and Technology, 2009, 43(24):9237-9244.
[17] Armitage J M, Schenker U, Scheringer M, et al. Modeling the global fate and transport of perfluorooctane sulfonate (PFOS) and precursor compounds in relation to temporal trends in wildlife exposure[J]. Environmental Science and Technology, 2009, 43(24): 9274-9280.
[18] Prevedouros K, Cousins I T, Buck R C, et al. Sources,fate and transport of perfluorocarboxylates[J]. Environmental Science and Technology, 2006, 40(1): 32-44.
[19] Wang Yawei, Fu Jianjie, Wang Thanh, et al. Distribution of perfluorooctane sulfonate and other perfluorochemicals in the ambient environment around a manufacturing facility in China[J].Environmental Science and Technology, 2010, 44(21) :8062-8067.
[20] Zhang Hong,Chen Qingwu,Yao Dan, et al. Feasibility to monitor environmental organofuorine pollutants using typical plants[J]. Journal of Shenzhen University Science and Engineering,2013,30(1):35-41.(in Chinese)
张鸿,陈清武,姚丹,等.用典型植物监测环境中有机氟污染物的可行性[J].深圳大学学报理工版,2013,30(1):35-41.
[21] Yoo H, Yamashita N, Taniyasu S, et al. Perfluoroalkyl acids in marine organisms from Lake Shihwa, Korea[J]. Archives of Environmental Contamination and Toxicology, 2009, 57(3) :552-560.
[22] Plumlee M H, Larabee J, Reinhard M. Perfluorochemicals in water reuse[J]. Chemosphere, 2008, 72(10) : 1541-1547.
[23] Jonathan P B, Amila O D, Jonathan W M. Isomer profiling of perfluorinated substances as a tool for source tracking:a review of early findings and future applications[J]. Reviews of Environmental Contamination and Toxicology, 2010, 208: 111-160.
[24] Lin A Y, Panchangam S C, Lo C C. The impact of semiconductor, electronics and optoelectronic industries on downstream perfluorinated chemical contamination in Taiwanese rivers[J]. Environmental Pollution, 2009, 157(4):1365-1372.
[25] Dinglasan M J, Ye Y, Edwards E A, et al.Fluorotelomer alcohol biodegradation yields poly- and perfluorinated acids[J]. Environmental Science and Technology, 2004, 38(10) :2857-2864.
[26] Zhu Lingyan, Lin Jiahua. Pollution trend and environmental behavior of perfluorooctanoic acid: a review[J]. Chinese Journal of Applied Ecology, 2008, 19(5):1149-1157.(in Chinese)
祝凌燕, 林加华. 全氟辛酸的污染状况及环境行为研究进展[J]. 应用生态学报,2008, 19(5):1149-1157.
[27] Hart K, Kannana K, Tao L, et al.Skipjack tuna as a bioindicator of contamination by perfluorinated compounds in the oceans[J]. Science of the Total Environment, 2008, 403(1/2/3) :215-221.
[28] Ellis D A, Martin J W, De Silva A O, et al.Degradation of fluorotelomer alcohols: a likely atmospheric source of perfluorinated carboxylic acids[J]. Environmental Science and Technology, 2004, 38(12):3316-3321.
[29] Becker A M, Gerstmann S, Frank H. Perfluorooctane surfactants in wastewaters, the major source of river pollution[J]. Chemosphere, 2008, 72(1) :115-121.
[30] Strynar M J, Lindstrom A B. Perfluorinated compounds in house dust from Ohio and North Carolina, USA[J]. Environmental Science and Technology,2008,42(10): 3751-3756.

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备注/Memo

备注/Memo:
Received:2014-03-26;Accepted:2014-05-26
Foundation:National Natural Science Foundation of China (11275130, 21177089)
Corresponding author:Professor Zhang Hong.E-mail: zhangh@szu.edu.cn
Citation:Zhao Liang, Zhang Hong, Zheng Zheng,et al.Perfluorinated compounds pollution fingerprints in typical industries of Shenzhen[J]. Journal of Shenzhen University Science and Engineering, 2014, 31(5): 537-543.(in Chinese)
基金项目:国家自然科学基金资助项目(11275130, 21177089)
作者简介:赵亮(1988—),男(汉族),湖南省湘乡市人,深圳大学硕士.E-mail:zhaoliang19880425@163.com
引文:赵亮, 张鸿, 郑正,等. 深圳市典型行业全氟化合物特征污染指纹[J]. 深圳大学学报理工版,2014,31(5):537-543.
更新日期/Last Update: 2014-09-11