[1]王成云,樊秀荣,黄明珠,等.2,4-二氨基甲苯及其同分异构体含量的快速测定[J].深圳大学学报理工版,2014,31(3):252-257.[doi:10.3724/SP.J.1249.2014.03252]
 Wang Chengyun,Fan Xiurong,Huang Mingzhu,et al.Rapid determination of 2,4-diaminotoluene and its isomers[J].Journal of Shenzhen University Science and Engineering,2014,31(3):252-257.[doi:10.3724/SP.J.1249.2014.03252]
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2,4-二氨基甲苯及其同分异构体含量的快速测定()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第31卷
期数:
2014年第3期
页码:
252-257
栏目:
化学与化工
出版日期:
2014-05-20

文章信息/Info

Title:
Rapid determination of 2,4-diaminotoluene and its isomers
作者:
王成云樊秀荣黄明珠阮营花沈雅蕾谢堂堂
深圳出入境检验检疫局工业品检测技术中心,深圳 518067
Author(s):
Wang Chengyun Fan Xiurong Huang Mingzhu Ruan Yinghua Shen Yalei and Xie Tangtang
The Testing and Technology Center for Industrial Products, Shenzhen Entry-Exit Inspection and Quarantine Bureau, Shenzhen 518067, P.R.China
关键词:
分析化学超高效液相色谱法24-二氨基甲苯禁用偶氮染料同分异构体快速测定纺织品假阳性干扰
Keywords:
analytical chemistry ultra-high performance liquid chromatography 24-diaminotoluene banned azo dyes isomer rapid determination textile false positive interference
分类号:
O 657.7+2
DOI:
10.3724/SP.J.1249.2014.03252
文献标志码:
A
摘要:
建立一种超高效液相色谱方法,可对2,4-二氨基甲苯及其同分异构体进行快速分离鉴定,排除了非禁用的同分异构体对禁用初级芳香胺2,4-二氨基甲苯测定的干扰. 该方法的加标回收率为63.67%~78.90%,精密度实验相对标准偏差值均小于5%. 在信噪比(S/N)=3的条件下,2,3-二氨基甲苯、2,4-二氨基甲苯、2,6-二氨基甲苯和3,4-二氨基甲苯的检出限分别为1.0、0.5、0.5和1.0 μg/mL. 该方法简便快速,分析耗时不到5 min,定性可靠、定量准确,可有效解决禁用偶氮染料检测中2,4-二氨基甲苯的假阳性问题.
Abstract:
In order to avoid the interference of the non-banned isomers on the determination of 2,4-diaminotoluene, an effective ultra-high performance liquid chromatography (UPLC) method was established. The spiked recoveries ranged from 63.67% to 78.90% while the relative standard deviation (RSD) of precision experiments all registered less than 5%. Under the condition of signal to noise S/N=3, the detection limit was 1.0, 0.5, 0.5 and 1.0 g/mL for 2,3-diaminotoluene, 2,4-diaminotoluene, 2,6-diaminotoluene and 3,4-diaminotoluene, respectively. Tests show that the proposed method is simple and rapid, only needing less than 5 minutes for the analysis procedure. This method is therefore reliable and accurate in quantity, and it also solves effectively the false positive problem in the analysis of 2,4-diaminotoluene.

参考文献/References:

[1] Burgi C, Bolhakler R, Otz T. HPLC method for the determination of aromatic amines released from water-thinned colors under phtsiological conditions[J]. Bundesam Fuer Gesundheitswesen, 1997, 88(3): 305-320.
[2] Lu Jie, Yang Dajin, Ge Zhiliang, et al. Method of detecting poisionous arylamine-2,4-diaminotoluene in composite food packaging[J]. Chinese Journal of Health Laboratory Technology, 2007, 17(10): 1743-1745.(in Chinese)
鲁杰,杨大进,葛志亮,等. 复合食品包装制品中有毒芳香胺-2,4-二氨基甲苯的检测技术研究[J]. 中国卫生检验杂志,2007,17(10): 1743-1745.
[3] GB 18401—2010 National general satefy technical code for textile products[S]. Beijing: China Standard Press, 2010: 1-7.(in Chinese)
GB 18401-2010 国家纺织产品基本安全技术规范[S]. 北京:中国标准出版社,2010:1-7.
[4] Directive 2002/61/EC of the European Parliament and of the Council of 19 July 2002 amending for the nineteenth time Council Directive 76/769/EEC relating to restrictions on the marketing and use of certain dangerous substances and preparations (azocolourants)[S]. Official Journal of the European Communities, L243: 15-18.
[5] Zhou Xuehui, Chen Zhicong, Li Junfa. Analysis on EU RAPEX notification of Chinese export garments[J]. China Textile Leader, 2010(3): 27-29.(in Chinese)
周雪晖,陈智聪,李军法. 欧盟RAPEX预警系统对中国服装通报情况分析[J]. 中国纺织导报,2010(3): 27-29.
[6] Gao Ming. REACH textiles recall case studies[J]. Dyeing & Finishing, 2011, 37(4): 40-42.(in Chinese)
高铭. REACH纺织品召回案例评析[J]. 印染,2011,37(4): 40-42.
[7] Lu Yang, Wang Fang, Shen Jinjin. Discussion on the safety requirement of textiles & garments based on analysis of EU RAPEX notification[J]. China Fiber Inspection, 2013(12): 30-33.(in Chinese)
卢鸯,王芳,沈金金. 从欧盟RAPEX通报情况谈纺织服装安全要求[J]. 中国纤检,2013(12): 30-33.
[8] Lu Yang, Ye Linhong, Han Gaofeng. Study on improving the accuracy of the banned azo colourants content test[J]. China Fiber Inspection, 2011(10): 56-58.(in Chinese)
卢鸯,叶琳虹,韩高锋. 提高禁用偶氮染料检测准确性探讨[J]. 中国纤检, 2011(10): 56-58.
[9] Cui Qinghua, Hao Yong, Yang Xiaoyong, et al. The detection method of textile banned azo dyes[J]. China Fiber Inspection, 2010(10): 66-68.(in Chinese)
崔庆华,郝永,杨晓勇,等. 纺织品禁用偶氮染料检测方法研究[J]. 中国纤检,2010(10): 66-68.
[10] Mao Minghua, Yang Lisheng. Results and reviews of prohibited azo colorants detected in submitted samples[J]. Wool Textile Journal, 2007(6): 51-54.(in Chinese)
茅明华,杨力生. 纺织品中含禁用偶氮染料的情况及分析[J]. 毛纺科技,2007(6): 51-54.
[11] Hu Xiaozhong, Yu Jianxin, Ni Lansun, et al. Identification method of false positive result in the detection of prohibited azo dyes[J]. Chinese Journal of Analytical Chemistry, 2000, 28(4): 411-416.(in Chinese)
胡小钟,余建新,倪澜荪,等. 禁用偶氮染料检测中假阳性结果的鉴定方法[J]. 分析化学, 2000, 28(4): 411-416.
[12] GB/T 5009.119—2003 Determination of diaminomethylbenzen of complex for food packaging materials[S]. Beijing: China Standard Press, 2003: 93-96.(in Chinese)
GB/T 5009.119—2003 复合食品包装袋中二氨基甲苯的测定[S]. 北京:中国标准出版社,2003:93-96.
[13] Chen Xiaomei, Zheng Ziqiang, Shi Xuxia. Determination of prohibited azo dyes in leather and textile materials by HPLC[J]. Journal of Instrumental Analysis, 1998, 17(4): 50-53.(in Chinese)
陈笑梅,郑自强,施旭霞. 染色皮革纺织品上禁用偶氮染料的高效液相色谱测定方法[J]. 分析测试学报,1998,17(4): 50-53
[14] Wang Chengyun, Zhang Weiya, Yang Zuojun, et al. Rapid determination of banned AZO dyes in textiles with UPLC[J]. Textile Dyeing and Finishing Journal, 2010, 32(11): 35-38.(in Chinese)
王成云,张伟亚,杨左军,等. 超高效液相色谱法测定纺织品中禁用偶氮染料[J]. 染整技术,2010, 32(11): 35-38.
[15] GB/T 17592—2011 Textiles-Determination of the banned azo colourants[S]. Beijing: China Standard Press, 2011: 1-10.(in Chinese)
GB/T 17592—2011纺织品禁用偶氮染料的测定[S]. 北京:中国标准出版社,2011:1-10.
[16] EN 14362-1:2012 Textiles-Methods for the determination of certain aromatic amines derived from azo colorants-Part 1: Detection of the use of certain azo colorants accessible with and without extracting the fibres[S]. London: British Standards Institution, 2012: 1-29.
[17] Wang Chengyun, Wu Touming, Xie Tangtang, et al. Rapid determination of o-toluidine and its isomers in textiles by ultra performance liquid chromatography[J]. Textile Science Technology, 2011, 12(2): 46-49.(in Chinese)
王成云,吴透明,谢堂堂,等. 高效液相色谱法测定纺织品邻甲苯胺含量[J]. 纺织科技精粹,2011, 12(2): 46-49.
[18] Wang Chengyun, Xie Tangtang, Shen Yalei, et al. Rapid determination of 1-naphthalenamine and 2-naphthalen-amine in textiles by ultra performance liquid chromatography[J]. Textile Standard and Quality, 2010(6): 30-32.(in Chinese)
王成云,谢堂堂,沈雅蕾,等. 超高效液相色谱法快速测定纺织品中的1-萘胺和2-萘胺[J]. 纺织标准与质量,2010(6): 30-32.
[19] Wang Chengyun, Shen Yalei, Lin Junfeng, et al. Determination of o-anisidine and its isomers by high performance liquid chromatography[J]. Shanghai Textile Science & Technology, 2013, 41(7): 56-58.(in Chinese)
王成云,沈雅蕾,林君峰,等. 邻氨基苯甲醚及其同分异构体的高效液相色谱法测定[J]. 上海纺织科技,2013,41(7): 56-58.
[20] Wang Chengyun, Xie Tangtang, Yang Zuojun, et al. Determination of triclosan in textiles by ultra performance liquid chromatography[J]. Journal of Instrumental Analysis, 2010, 29(12): 1231 -1234.(in Chinese)
王成云,谢堂堂,杨左军,等. 超高效液相色谱法测定纺织品中三氯生的含量[J]. 分析测试学报,2010,29(12): 1231- 1234.

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备注/Memo

备注/Memo:
Received:2014-02-07;Accepted:2014-04-08
Foundation:AQSIQ Science and Technology Plan (2012IK119)
Corresponding author:Professor Wang Chengyun. E-mail: wangchengyun2009@126.com
Citation:Wang Chengyun, Fan Xiurong, Huang Mingzhu,et al. Rapid determination of 2,4-diaminotoluene and its isomers[J]. Journal of Shenzhen University Science and Engineering, 2014, 31(3): 252-257.(in Chinese)
基金项目:国家质检总局科技计划资助项目(2011IK119)
作者简介:王成云(1969—),男(汉族),湖南省新化县人,深圳出入境检验检疫局工业品检测技术中心研究员、博士. E-mail: wangchengyun2009@126.com
引文:王成云,樊秀荣,黄明珠,等. 2,4-二氨基甲苯及其同分异构体含量的快速测定[J]. 深圳大学学报理工版,2014,31(3):252-257.
更新日期/Last Update: 2014-05-04