[1]李鱼,等.引入Cu2+的沉积物吸附阿特拉津多元回归模型[J].深圳大学学报理工版,2012,29(No.1(001-094)):7-11.[doi:10.3724/SP.J.1249.2012.01007]
　LI Yu,WANG Meng,GAO Qian,et al.Establishment of a multiple regression adsorption model for atrazine adsorption onto the surficial sediments with Cu2+ present[J].Journal of Shenzhen University Science and Engineering,2012,29(No.1(001-094)):7-11.[doi:10.3724/SP.J.1249.2012.01007]
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引入Cu2+的沉积物吸附阿特拉津多元回归模型()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第29卷
期数:
2012年No.1(001-094)
页码:
7-11
栏目:
环境与能源
出版日期:
2012-01-06

文章信息/Info

Title:
Establishment of a multiple regression adsorption model for atrazine adsorption onto the surficial sediments with Cu2+ present
作者:
李鱼1;  2; 王檬1;  2; 高茜1;  2; 李珊珊1;  2
1) 华北电力大学区域能源系统优化教育部重点实验室，北京 102206
2) 华北电力大学能源与环境研究院，北京 102206
Author(s):
LI Yu1; 2;  WANG Meng1; 2;  GAO Qian1; 2;  and LI Shan-shan1; 2
1) Key Laboratory of Regional Energy Systems Optimization, Ministry of Education, North China Electric Power University, Beijing 102206, P.R.China
2) Research Academy of Energy and Environmental Studies, North China Electric Power University, Beijing 102206, P.R.China
关键词:
环境化学; 多元回归吸附模型; 重金属复合污染; 沉积物; 铜; 阿特拉津; 除草剂
Keywords:
environmental chemistry;  multiple regression adsorption models(MRAM);  heavy metal composite contamination;  surficial sediments;  copper(Cu);  atrazine;  herbicide
分类号:
X 132
DOI:
10.3724/SP.J.1249.2012.01007
文献标志码:
A
摘要:
为揭示重金属存在条件下沉积物（生物膜）吸附阿特拉津（atrazine, AT）的复合污染规律，通过编程研究筛选优化沉积物吸附AT多元回归吸附模型（atrazine-multiple regression adsorption model ，AT-MRAM），以定性变量的方式将共存的Cu2+（外因）引入模型中，建立包含Cu2+影响的沉积物吸附AT-Cu2+-MRAM．经分析发现，Cu2+的存在会抑制AT在沉积物上的吸附，且Cu2+质量浓度越大其抑制作用越强，Cu2+质量浓度为75 mg/L时的抑制程度比15 mg/L时的抑制程度提高1倍以上；Cu2+对沉积物组分（铁氧化物和有机质）的吸附能力产生一定影响，会使各组分的吸附能力减弱8.75%～19.40%．
Abstract:
In order to reveal characteristic of atrazine (AT) adsorption onto the surficial sediments (the natural surficial coating samples) in the copper/AT composite contamination system, Cu2+ (external) as a qualitative variable was introduced into the multiple regression adsorption model(MRAM), and a new AT-Cu2+-MRAM was developed. It is found that copper caused antagonistic effect on AT adsorption, the inhibition is generally enhanced with the increase of copper levels, and the inhibition with Cu2+ present at level of 75 mg/L is one time more than that with Cu2+ present at level of 15 mg/L. Also, Cu2+ can affect the AT adsorption onto the main components (such as Fe oxides and organic materials) in surficial sediments (the natural surficial coating samples), decreasing the AT adsorption onto the main components by 8.75%~19.40%.

参考文献/References:

［1］ Jantunen A P K, Tuikka A. Bioaccumulation of atrazine and chlorpyrifos to Lumbriculus variegates from lake sediments［J］. Ecotoxicology and Enviromental Safety, 2008, 71: 860-868.
［2］ LI Yu, GAO Qian. Synergetic and antagonistic effects of cadmium on the adsorption of atrazine in the surficial sediments［J］. Chemical Research in Chinese Universities, 2009, 25(2):155-160.
［3］ LI Yu, WANG Ao, GAO Qian. Measurement of atrazine adsorptionontosurficialsedimentsnaturalsurfacecoatings-new evidence for the importance of Fe oxides［J］. Chemical Research in Chinese Universities, 2009, 25(1): 31-36.
［4］ DONG De-ming, Nelson Y M, Lion L W.Adsorption of Pb and Cd onto metal oxides and organic material in natural surface coatings as determined by selective extractions: new evidence for the importance of Mn and Fe oxides［J］.Water Research, 2000, 34(2): 427-436.
［5］ LI Yu, WANG Xiao-li, ZHANG Zheng, et al. Selective extraction and separation of non-residual components in the surficial sediments(surfacecoatings)andadsorptioncharacteristicsof Cu and Zn ［J］. Chemical Journal of Chinese Universities, 2006, 27(12): 2285-2290.(in Chinese)
李鱼, 王晓丽, 张正, 等. 表层沉积物（生物膜)非残渣态组分的选择性萃取分离及其吸附铜/锌的特性［J］. 高等学校化学学报, 2006, 27(12): 2285-2290.
［6］ LI Shan-shan, GAO Qian, WANG Xiao-li,et al. Using multiple regression adsorption models to estimate Zn and Cu adsorptions onto Fe oxides, Mn oxides, organic materials and their blends in surficial sediments［J］. Fresenius Environmental Bulletin, 2009, 19(8): 1466-1473.
［7］ LI Yu, LI Shan-shan, GAO Qian,et al. Effect of interaction of non-residual fractions on atrazine adsorption onto surficial sediments and natural surface coating samples［J］. Chemical Research in Chinese Universities, 2011, 27(2), 212-216.
［8］ WANG Ao. Studies on the Effects of Coexisted Contaminants on the Adsorption Characteristics of Atrazine onto the Surficial Sediments and Their Main Components［D］. Changchun: Jilin University, 2009.(in Chinese)
王岙. 共存污染物对沉积物及其主要组分吸附阿特拉津的影响研究［D］. 长春: 吉林大学, 2009.
［9］ DONG De-ming, LIU Liang, HUA Xiu-yi, et al. Comparison of lead, cadmium, copper and cobalt adsorption onto metal oxides and organic materials in natural surface coatings［J］. Microchemical Journal, 2007, 85(2): 270-275.
［10］ GAO Qian, WANG Ao, LI Yu. Combined effect of co-existing heavy metals and organophosphate pesticide on absorption of atrazine to river sediments［J］. Korean Journal of Chemical Engineering, 2011, 28(5): 1200-1206.

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备注/Memo

备注/Memo:
Received：2011-05-26；Accepted：2011-11-25
Foundation：National Natural Science Foundation of China (50879025)
Corresponding author：Professor LI Yu. E-mail：liyuxx@jlu.edu.cn
Citation：LI Yu, WANG Meng, GAO Qian, et al. Establishment of a multiple regression adsorption model for atrazine adsorption onto the surficial sediments with Cu2+ present［J］. Journal of Shenzhen University Science and Engineering, 2012, 29(1): 7-11.（in Chinese）
基金项目：国家自然科学基金资助项目（50879025）
作者简介：李鱼，男（汉族），吉林省长春市人，华北电力大学教授、博士生导师. E-mail：liyuxx@jlu.edu.cn
引文：李鱼，王檬，高茜，等．引入Cu2+的沉积物吸附阿特拉津多元回归模型［J］. 深圳大学学报理工版，2012，29（1）：7-11.
更新日期/Last Update: 2012-01-05