[1]韩彬,等.金刚烷类风化规律及其在油源鉴别中的应用[J].深圳大学学报理工版,2011,28(No.4(283-376)):362-367.
 HAN Bin,CAO Lei,et al.Weathering regularities of diamondoids and their applications to oil source identification[J].Journal of Shenzhen University Science and Engineering,2011,28(No.4(283-376)):362-367.
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金刚烷类风化规律及其在油源鉴别中的应用()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第28卷
期数:
2011年No.4(283-376)
页码:
362-367
栏目:
环境与能源
出版日期:
2011-07-20

文章信息/Info

Title:
Weathering regularities of diamondoids and their applications to oil source identification
文章编号:
1000-2618(2011)04-0362-06
作者:
韩彬1 2曹磊1郑立1李景喜1王小如1
1)国家海洋局第一海洋研究所 海洋生态研究中心,山东青岛 266061
2)大连理工大学海岸及近海工程国家重点实验,辽宁大连 116024
Author(s):
HAN Bin1 2CAO Lei1ZHENG Li1 LI Jing-xi1and WANG Xiao-ru1
 1)First Institute of Oceanography, State Oceanic Administration, Shangdong Province, Qingdao 266061, P.R.China
2)State Key laboratory of Coastal and offshore engineering, Dalian University of Techonlogy, Liaoning Province, Dalian 116024, P.R.China
关键词:
有机地球化学溢油事故海面溢油风化风化模拟气相色谱质谱联用金刚烷溢油指纹鉴别
Keywords:
organic geochemistryoil spill accidentspilled oil weathering on the seaweathering simulationgas chromatography-mass spectrometry (GC-MS)diamondoidsfingerprinting identification for spilled oil
分类号:
X 131.2;TE 122.1
文献标志码:
A
摘要:
以渤海常青号原油为研究对象进行综合模拟风化实验,通过气相色谱质谱对风化样品中金刚烷类进行检测;通过图谱和风化特征分析,探讨了原油中金刚烷类化合物的风化规律.结果表明,经历50 d风化,渤海原油单金刚烷类稳定性为:四甲基单金刚烷>三甲基单金刚烷>二甲基单金刚烷>一甲基单金刚烷>单金刚烷;双金刚烷类稳定性为:二甲基双金刚烷>一甲基双金刚烷>双金刚烷,且双金刚烷类抗风化能力普遍强于单金刚烷类.经t检验和重复性限法分析,所筛选的23个金刚烷类诊断比值指标经历50 d风化仍保持良好的稳定性,可作为油源的鉴别指标.
Abstract:
The Changqinghao oil from Bohai Sea was taken to make a comprehensive weathering simulation experiment, and the gas chromatography-mass spectrometry was used to detect the diamondoids in the oil samples. The weathering regularities of diamondoids in the oil samples were explored by analyzing the spectra and weathering features of diamondoids. After 50 days weathering, the analysis results show that the stabilities of adamantanes in the oil samples arranged in the order of magnitude are: tetramethyladamantane, trimethyladamantane, dimethyladamantane, methyladamantane and adamantane; and the stabilities of diamantanes arranged in the order of magnitude are: tetramethyldiamantane, trimethyldiamantane, dimethyldiamantane, methyldiamantane and diamantane. The anti-weathering abilities of diamantanes are greater than those of adamantanes in general. From the analysis results of t-test (student’s t test) and repeatability limit method,  it is shown that the 23 selected diagnositic ratios indices of diamondoids still maintained better stabilities after weathering for 50 days. These diognostic indices can be used for the identification of oil source.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2011-01-30;修回日期:2011-03-29
基金项目:国家自然科学基金资助项目(41076108)
作者简介:韩彬(1979-),男(汉族),河南省新乡市人,国家海洋局第一海洋研究所助理研究员.E-mail:hanbin@fio.org.cn
通讯作者:王小如(1949-),女(汉族),国家海洋局第一海洋研究所教授、博士生导师.E-mail:mt2elp@fio.org.cn
更新日期/Last Update: 2011-07-22