[1]郭玉文,王松涛,刘景洋,等.废电线热解过程产物分析[J].深圳大学学报理工版,2009,26(3):246-250.
 GUO Yu-wen,WANG Song-tao,LIU Jing-yang,et al.The thermal decomposition of waste computer wire[J].Journal of Shenzhen University Science and Engineering,2009,26(3):246-250.
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废电线热解过程产物分析()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第26卷
期数:
2009年3期
页码:
246-250
栏目:
环境与能源
出版日期:
2009-07-31

文章信息/Info

Title:
The thermal decomposition of waste computer wire
文章编号:
1000-2618(2009)03-0246-05
作者:
郭玉文1王松涛12刘景洋1乔琦1张建强2王红梅1
1)中国环境科学研究院,北京 100012;
2)西南交通大学环境科学与工程学院,成都 610031
Author(s):
GUO Yu-wen1WANG Song-tao12LIU Jing-yang1QIAO Qi1ZHANG Jian-qiang2and WANG Hong-mei1
1)Chinese Research Academy of Environmental Sciences,Beijing 100012,P.R.China
2)The College of Environmental Science and Engineering,Southwest Jiaotong University,Chengdu 610031,P.R.China
关键词:
电子废弃物废电线焚烧热解有机污染物环境保护
Keywords:
waste electric and electronic equipment(WEEE)waste wireincineration pyrolysisorganic pollutantsenvironmental protection
分类号:
X 705
文献标志码:
A
摘要:
模拟研究了废电脑电线热解特性和热处理产物.结果表明,废电脑电线热解过程出现3个剧烈失重阶段,第1剧烈失重阶段主要是聚合物分解,第2剧烈失重阶段主要是增塑剂分解,阻燃剂分解持续整个实验过程.废电脑电线热解产物既有6~16个C原子的油状有机物,也有烃类小分子有机化合物、有机氯化物和HCl.热解产物中有多种毒害物质,必须加以控制.
Abstract:
The pyrolysis characteristics,thermal decomposition products from waste computer wire were simulant studied.Results show that waste computer wire has three acutely weight loss stages, of which the first is decomposing of the organic polymer,the second is decomposing of the Plasticizer,and decomposing of flame retardants persists throughout the experiment.A variety of organic compounds could probably be produced in the thermal decomposition,such as aromatic oil compounds comprised 6~16 caibon atom,little numerator organic compounds,chloridized organic compounds and HCl.The pyrolysis products have diversiform poisonous and toxic sudstances. Its pollution controlling is necessary.

参考文献/References:

[1]胡涛,吴玉萍,张凌云. 我国固体废物的管理体制问题分析[J].环境科学研究,2006,19(S1):33-39.
[2]王琪,黄启飞,段华波,等. 我国危险废物特性鉴别技术体系研究[J].环境科学研究,2006,19(5):165-179.
[3]Zhu H M,Jiang X G,Yan J H,等. 热重-红外联用分析聚氯乙烯热解产物及氯化氢去除研究[J].热解分析与应用,2008,82(1):1-9(英文版).
[4]Basfar A A. 偶联聚氯乙烯阻燃剂用于电线电缆绝缘材料研究[J]. 聚合物降解与稳定性,2002,77(2):221-226(英文版).
[5]张翔,李风,王玉忠,等.阻燃聚氯乙烯电线绝缘材料的热分解动力学研究[J].绝缘材,2007,40(3): 52-57.
[6]林华影,林瑶,张伟.气相色谱-质谱法分析聚氯乙烯加热分解产物[J].中国卫生检验杂志,2008,18(4):587-589
[7]Ebert J,Bahadir M. 含阻燃剂塑料热压条件下多溴代二恶英/呋喃产物组成研究[J]. 国际环境,2003,29:711-716(英文版).
[8]Junichiro Hayashi,Takeshi Nakahara,Katsuki Kusakabe. 有氧氛围聚丙稀热解研究[J].煤炭转化,1998,55:265-275.

[1]HU Tao,WU Yu-ping,ZHANG Ling-yun. Environmental governance analysis of China’s solid wastes management [J]. Research of Environmental Sciences,2006,19(S1):33-39(in Chinese).
[2]WANG Qi,HUANG Qi-fei,DUAN Hua-bo,et al. Study on technical system of China for identification of hazardous wastes[J]. Research of Environmental Sciences,2006,19(5):165-179(in Chinese).
[3]Zhu H M,Jiang X G,Yan J H,et al.TG-FTIR analysis of PVC thermal degradation and HCl removal[J].Journal of Analytical and Applied Pyrolysis,2008,82(1): 1-9.
[4]Basfar A A.Flame retardancy of radiation cross-linked poly(vinyl chloride) (PVC) used as an insulating material for wire and cable[J].Polymer Degradation and Stability.2002,77( 2): 221-226.
[5]ZHANG Xiang,LI Feng,WANG Yu-zhong,et al.Study on thermal degradation kinetics of fire retardant PVC for cable insulation[J].Insulating Materials,2007,40(3): 52-57(in Chinese).
[6]LIN Hua-ying,LIN Yao,ZHANG Wei.Analysis of pyrolysis products of polyvinyl chloride(PVC)by GC-MS[J].Chinese journal of Health Laboratory Technology,2008,4(18):587-589(in Chinese).
[7]Ebert J,Bahadir M. Formation of PBDD/F from flame-retarded plastic materials under thermal stress[J]. Environmental International,2003,29:711-716.
[8]Junichiro Hayashi,Takeshi Nakahara,Katsuki Kusakabe.Pyrolysis of polypropylene in the presence of oxygen[J].Fuel Processing Techndogy,1998,55:265-275.

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备注/Memo

备注/Memo:
收稿日期:2009-03-01;修回日期:2009-07-06
基金项目:环境保护部公益基金资助项目(HBGY200709022);中国环境科学研究院科研业务专项资助项目(2007KYYW02)
作者简介:郭玉文(1967-),男(汉族),河北省承德县人,中国环境科学研究院副研究员、博士.E-mail: guoyw@craes.org.cn
更新日期/Last Update: 2009-08-11