[1]王 雷,朱光明,高春梅.用于质子交换膜的三个苯环磺化聚芳醚的合成[J].深圳大学学报理工版,2007,24(3):305-308.
 WANG Lei,ZHU Guang-ming,and GAO Chun-mei.Synthesis and characterization of sulfonatedpoly(arylene ether) containing triphenyl moietiesfor proton exchange membrane[J].Journal of Shenzhen University Science and Engineering,2007,24(3):305-308.
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用于质子交换膜的三个苯环磺化聚芳醚的合成()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第24卷
期数:
2007年3期
页码:
305-308
栏目:
化学与化工
出版日期:
2007-07-30

文章信息/Info

Title:

Synthesis and characterization of sulfonatedpoly(arylene ether) containing triphenyl moietiesfor proton exchange membrane

文章编号:
1000-2618(2007)03-0305-04
作者:
王 雷1朱光明1高春梅2
1)深圳市特种功能材料重点实验室,深圳大学材料学院,深圳 518060;
2)中国科学院广州化学所,广州 510650
Author(s):
WANG Lei1ZHU Guang-ming1and GAO Chun-mei2

1)College of Materials Science and Engineering,Shenzhen University and Shenzhen Key Laboratory of Special Functional Materials,Shenzhen University,Shenzhen 518060,P. R China
2)Guangzhou Institute of Chemistry,Chinese Academy of Sciences,Guangzhou 510650,P. R. China

关键词:
磺化聚芳醚质子交换膜质子交换膜燃料电池
Keywords:
sulfonated poly(arylene ether) proton exchange membraneproton exchange membrane fuel cell
分类号:
TB 324;U 465.4
文献标志码:
A
摘要:

合成一种含三个苯环的新型磺化聚芳醚.采用特殊单体结构的设计,在聚合物主链上引入甲基取代基对主链进行保护.用氯磺酸直接磺化方法在聚芳醚高分子侧基上引入磺酸功能基,实现了聚合物磺化结构的可控定位合成,得到了磺酸基在侧链上的磺化聚芳醚.通过核磁共振(1H-NMR)、凝胶渗透色谱(GPC)和元素分析(EA)等方法,对其结构进行表征.

Abstract:

Novel sulfonated poly(arylene ether) containing triphenyl moieties as polymer electrolyte for fuel cell application was successfully synthesized. The sulfonic acid function was only attached at the para positions on the pendant phenyl rings due to the novel sulfonated poly(arylene ether) structures designed. The sulfonated polymers are characterized by 1H-NMR,Gel permeation chromatography (GPC) analyses,Elemental analyses(EA) and can be potentially used as the proton-exchange membranes for fuel-cells.

参考文献/References:

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[3] 刘盛洲,王? 烽,陈天禄. 高磺化度芳香聚醚醚酮的合成与表征[J].高等学校化学学报,2001,22(3):494-497.
[4] 李翠华,刘剑洪,管? 蓉,等. 加热和拉伸对磺化聚芳醚膜导电性能的影响[J].武汉理工大学学报,2006,28:543-547.
[5]Miyatake K,Chikashige Y,Watanabe M. 磺化聚芳醚:一种为燃料电池设计的聚合物电解质[J].大分子,2003,36(26):9691-9693(英文版).
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[1]Steele B C H,Heinzel A. Materials for fuel-cell technologies[J].Nature,2001,414:345-352.
[2]Stevice R F. Hewcomer heats up the race for practical fuel cells [J].Science,2004,303:29-30.
[3]LIU Sheng-zhou,WANG Feng,CHEN Tian-lu. Synthesis and characterization of a series of high sulfonated poly(ether ether ketone)s[J].Chem J Chinese Universities,2001,22(3):494-497(in Chinese).
[4]LI Cui-hua,LIU Jian-hong,GUAN Rong,et al. Effect of heating and stretching membrane on ionic conductivity of sulfonated poly(phenylene oxide) [J].J Wuhan University of Technology,2006,28:543-547(in Chinese).
[5]Miyatake K,Chikashige Y,Watanabe M. Novel sulfonated poly(arylene ether):A proton conductive polymer electrolyte designed for fuel cells[J].Macromolecules,2003,36(26):9691-9693.
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更新日期/Last Update: 2007-12-07