用于聚丙烯插层的蒙脱土化学修饰与表征-《深圳大学学报理工版》

文章信息/Info

Title:: Chemical modification and characterization of montmorillonites applied for polypropylene nanocomposites

作者:: 倪卓¹; 刘剑洪¹; 宋军²; 邹恩广³; 王宝辉²; 1)深圳大学师范学院，深圳518060；
2)大庆石油学院，大庆163316；
3)大庆石化研究院，大庆163320

Author(s):: NI Zhuo1; LIU Jian-hong1; SONG Jun2; ZOU En-guang3; and WANG Bao-hui2; 1)Nornal College Shenzhen University
2)Daqing Petroleum University
3)Daqing Petroleum Chemicals Institute

Keywords:: polypropylene/montmorillonites; nanocomposites; alky1 ammonium; chemical modification; melting intercalation

摘要:: 采用长链季铵盐阳离子表面活性剂对钠基蒙脱土进行化学修饰,制得有机蒙脱土,采用红外(FT-IR)、X射线衍射(XRD)和热重分析(TGA)等手段,对有机化蒙脱土的结构进行表征.实验结果表明,长链季铵盐通过离子交换反应可有效修饰蒙脱土,有机阳离子置换掉蒙脱土层间的金属阳离子.蒙脱土经插层处理后,其晶层间距都比原始蒙脱土的层间距有所增加.由于有机阳离子体积较大,从而将蒙脱土片层撑开,层间距增大,减弱了蒙脱土片层间的静电吸引力和化学键合力,改善层间微环境,使粘土内外表面由亲水性转变为疏水性,降低硅酸盐表面能,有利于聚合物插入层间.

Abstract:: Polypropylene(PP)/montmorillonites(MMT)nanocomposites are applied in industrial production due to its improved properties. Chemical modification of MMT is a key technique in the manufacture of polymer nanocomposites. This investigation concentrated on the preparation of organic montmorillonites through a way of treatment of Na-montmorillonites using several long-chain alky1 quaternary ammonium ions. The result MMT were characterized by FT-IR 、XRD and TGA, etc. The results indicated that alkyl ammonium ions had been intercalated into the layered silicate of org-MMT. The layer spacing of MMT modified by hexadecy1 trimethy1 ammonium(HTAB) was increased most effectively. The structural changes in MMT layers formed a nanometer yardstick providing sufficient intercalation, resulting in good mechanical properties and improved crystallization behavior.