[1]姚彤彤.三核钌配合物中分子内电子转移[J].深圳大学学报理工版,1992,(3-4):21-31.
Yao Tongtong.Intramolecular Electron Transfer in Trinuclear Ruthenium Complex[J].Journal of Shenzhen University Science and Engineering,1992,(3-4):21-31.
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三核钌配合物中分子内电子转移(
)
《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]
- 卷:
-
- 期数:
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1992年3-4期
- 页码:
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21-31
- 栏目:
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环境与能源
- 出版日期:
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1992-12-31
文章信息/Info
- Title:
-
Intramolecular Electron Transfer in Trinuclear Ruthenium Complex
- 作者:
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姚彤彤
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万国软件开发(深圳)有限公司
- Author(s):
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Yao Tongtong
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International Software Development (Shenzhen) Co., Ltd.
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- 关键词:
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反式构型; 三核钌; 分子内电子转移; 价间转移带
- Keywords:
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Trans-configuration; Trinuclear ruthenium; Intramolecular electron transfer; Inter-valence transfer
- Abstract:
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Trinuclear Ruthenium complex of trans- configuration has been synthesized and characterized by element analysis，IR and UV-VIS spectrum. Different mixed valence complexes are obtained by Ce(SO4)2.The intramolecular electron transfer is studied with UV-VIS-N1R spectrum. Different kinds of transitions are found，including the inter-valence transfer(IT)between ruthenium atoms of adjacent moieties, The valence delocalization Parameter a2 and the electron matrix element HAB are calculated from the parameters of the IT spectrum.
更新日期/Last Update:
2016-05-10