[1]龚晓钟,田鹏,周智,等.稀土填充热电材料CoSb3Smx和CoSb3Prx的制备及表征[J].深圳大学学报理工版,2010,27(2):217-223.
 GONG Xiao-zhong,TIAN Peng,ZHOU Zhi,et al.Electrodeposition and characterization of rare-earth element filled thermoelectric material CoSb3Smx and CoSb3Prx[J].Journal of Shenzhen University Science and Engineering,2010,27(2):217-223.
点击复制

稀土填充热电材料CoSb3Smx和CoSb3Prx的制备及表征()
分享到:

《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第27卷
期数:
2010年2期
页码:
217-223
栏目:
化学与化工
出版日期:
2010-04-30

文章信息/Info

Title:
Electrodeposition and characterization of rare-earth element filled thermoelectric material CoSb3Smx and CoSb3Prx
文章编号:
1000-2618(2010)02-0217-07
作者:
龚晓钟1田鹏2周智1钟启鸣1汤皎宁2
1)深圳大学化学与化工学院 深圳市功能高分子重点实验室,深圳 518060
2)深圳大学材料学院 深圳市特种功能材料重点实验室,深圳 518060
Author(s):
GONG Xiao-zhong1TIAN Peng2ZHOU Zhi1ZHONG Qi-ming1and TANG Jiao-ning2
1)College of Chemistry and Chemical Engineering,Shenzhen Key Llaboratory of Functional Polymers,Shenzhen University,Shenzhen 518060,P. R.China
2)College of Materials Science and Engineering,Shenzhen Key Laboratory of Special Functional Materials,Shenzhen University,Shenzhen 518060,P. R.China
关键词:
电化学热电材料稀土元素脉冲电沉积填充式方钴矿低温熔融盐体系
Keywords:
electrochemistrythermoelectric materialrare-earth elementpulsed electrodeposition filled-Skutteruditefused salt system in low temperature
分类号:
O 614.41; TB 383
文献标志码:
A
摘要:
在低温熔融盐体系中,采用电沉积方法室温条件下制备Sm和Pr填充方钴矿化合物.研究不同稀土填充的方钴矿CoSb3热电材料的最佳制备工艺条件.通过扫描电子显微镜观察CoSb3Smx和CoSb3Prx的表面形貌,用特征X射线谱能确定其化学成分,用X射线衍射分析其晶型结构.优化工艺条件使稀土元素达到最大填充量.研究结果表明,合金薄膜的组成为Sm0.32CoSb3和Pr0.30CoSb3.三元合金薄膜由体心立方结构的CoSb3和六方晶形的稀土单质Sm组成.
Abstract:
Sm,Pr-filled Skutterudite was prepared by electrodeposition in ionic liquid at the room temperature.The optimum processing conditions for preparing Skutterudite filled with a variety of rare-earth elements, were investigated.Methods of equipment analysis,such as scanning electron microscopy,energy dispersive spectrometer,and X-ray diffraction,were employed to characterize the morphologies,the compositions,and the crystal structure of the above Skutterudites.Under the optimized reaction conditions,the amount of rare-earth element reached maximum with the composition of the alloy thin film as Sm0.32CoSb3 or Pr0.30CoSb3.Three-phase alloy thin film was composed of body-centered cubic CoSb3 and the hexagonal element Sm.

参考文献/References:

[1]褚颖.纳米方钴矿化合物的化学合成及其热电性能研究[D].武汉:武汉理工大学,2007.
[2]Morelli D T,Caillat T,Fleurial J,等.p型CoSb3的低温转变[J].物理评论:B,1995,51(15):9622-9628.(英文版)
[3]宋晨,唐新峰,刘桃香,等.Sm填充方钴矿化合物的合成及热电性能[J].武汉理工大学学报,2007,29(2):1-4.
[4]罗派峰,唐新峰,李涵,等.Ba和Ce两种原子复合填充BamCenFeCo3Sb12化合物的合成及热电性能[J].物理学报.2004,53(9):3234-3237.
[5]董楠,贾晓鹏,宿太超,等. Na填充型方钴矿化合物CoSb3的高压合成及电输运特性研究[J].高压物理学报.2009,23(1):42-45.
[6]刘桃香,唐新峰,邓书康,等.Ca和Sm双原子共填充方钴矿化合物的制备及热电性能[J].无机材料学报.2008.23(4):710-714.
[7]宋新莉,袁泽喜,刘静,等.机械合金化及等离子体烧结法制备Skutterudite热电材料FexCo4-xSb12[J].武汉科技大学学报自然科学版,2008,31(4):390-393.
[8]彭军.脉冲电镀Ni-Nd-P稀土合金薄膜的研究[D].长沙:湖南大学,2004.
[9]王玲玲,唐黎明,黄桂芳,等. 水溶液电沉积稀土合金膜的结构和性能研究[J].材料保护,2005,38(1):40-44.
[10]刘龙玉,郭忠诚,张 欢,等. 脉冲电沉积Ni-W-P系多元复合镀层性能研究[J].昆明理工大学学报理工版,2004,29(3):21-25.
[11]江琳才.欠电位沉积[J].化学通报,1988,(2):9-13.
[12]Wathirajan S S,Bruckenstein S.镍沉积层在被溶解时瞬时质量和与充放电量之间函数关系的测定[J].电化学学报,1983,8(5) :683-687.(英文版)
[13]梁文平,康晋.当代化学的一个重要前沿——绿色化学[J].化学进展,2000,12(5):228-230.
[14]Linus Pauling.化学键的本质[M].第3版,上海:上海科学技术出版社,1981:35-36.(英文版)
[15]敖伟琴,刘福生,李均钦,等. 纳米AgPb18SbTe20热电材料的合成[J].深圳大学学报理工版,2009,26(4):366-370.
[16]刘福生,敖伟琴,罗锐敏,等. Hf掺杂BiSbTe3结构与热电性能研究[J].深圳大学学报理工版,2008,25(3):299-302.



[1]CHU Ying.Synthesis and Thermoelectric Properties of Nano-Skutterudite Compounds by Chemical Methods[D].Wuhan:Wuhan University of Science and Engineering,2007.(in Chinese)
[2]Morelli D T,Caillat T,Fleurial J,et al.Low-temperature transport of p-type CoSb3[J].Physical Review B,1995,51(15):9622-9628.
[3]SONG Chen,TANG Xin-feng,LIU Tao-xiang,et al.The synthesis and thermoelectric properties of Samarium-filled Skutterudite SmyFexCo4-xSb12[J].Journal of Wuhan University of Technology,2007,29(2):1-4.(in Chinese)
[4]LUO Pai-feng,TANG Xin-feng,LI Han,et al.The synthesis and thermoelectric properties of double-atom-filled BamCenFeCo3Sb12 compounds [J].Journal of Physics,2004,53(9):3234-3237.(in Chinese)
[5]DONG Nan,JIA Xiao-peng,SU Tai-chao,et al.Synthesis and electric transport properties of Na-filled CoSb3 at high-pressure[J].Chinese Journal of High Pressure Physics,2009,23(1):42-45.(in Chinese)
[6]LIU Tao-xiang,TANG Xin-feng,DENG Shu-kang,et al.Synthesis and thermoelectric properties of the Ca and Sm Co-filled Skutterudites[J].Journal of Inorganic Materials,2008,23(4):710-714.(in Chinese)
[7]SONG Xin-li,YUAN Ze-xi,LIU Jing,et al.Synthesis of Skutterudite thermoelectric material FexCo4-xSb12 compound by mechanical alloying and spark plasma sintering[J].Journal of Wuhan University of Science and Technology Natural Science Edition,2008,31(4):390-393.(in Chinese)
[8]PENG Jun.Study on Electroplating of Ni-Nd-P Rare Earth Alloy Coating[D].Changsha:Hunan University,2004.(in Chinese)
[9]WANG Ling-ling,TANG Li-ming,HUANG Gui-fang,et al. Structure and properties of rare earth alloy coating electrodeposited in aqueous solution[J].Materials Protection,2005,38(1):40-44.(in Chinese)
[10]LIU Long-yu,GUO Zhong-cheng,ZHANG Huan,et al. Study on the properties of electrodeposition Ni-W-P series multi-composite coatings[J].Journal of Kunming University of Science and Technology,2004,29(3):21-25. (in Chinese)
[11]JIANG Lin-cai.Under potential deposition[J]. Chemistry,1988,(2):9-13.(in Chinese)
[12]Wathirajan S S,Bruckenstein S.Determination of time dependence of passive layer on nickel from instantaneous mass/charge function F(dm/dQ) in competitive passivation/dissolution conditions[J].Electrochemical Acta,1983,8(5) :683-687.
[13]LIANG Wen-ping,KANG Jin.Green chemistry:one of the important frontiers in chemistry[J].Progress in Chemistry,2000,12(5):228-230.(in Chinese)
[14]Linus Pauling.The Nature of the Chemical Bond[M].3rd edition,Shanghai:Science Press of Shanghai,1981:35-36.
[15]AO Wei-qin,LIU Fu-sheng,LI Jun-qin,et al. Nano-AgPb18SbTe20 synthesized by hydrothermal method[J].Journal of Shenzhen University Science and Engineering,2009,26(4):366-370. (in Chinese)
[16]LIU Fu-sheng,AO Wei-qin,LUO Rui-min,et al. Structure and thermoelectrical properties of Hf doped BiSbTe3 compounds[J].Journal of Shenzhen University Science and Engineering,2008,25(3):299-302. (in Chinese)

相似文献/References:

[1]敖伟琴,刘福生,李均钦,等.纳米AgPb18SbTe20热电材料的合成[J].深圳大学学报理工版,2009,26(4):366.
 AO Wei-qin,LIU Fu-sheng,LI Jun-qin,et al.Nano-AgPb18SbTe20 synthesized by hydrothermal method[J].Journal of Shenzhen University Science and Engineering,2009,26(2):366.
[2]范平,郑壮豪,梁广兴,等.离子束溅射制备Bi2Te3热电薄膜[J].深圳大学学报理工版,2011,28(No.1(001-095)):84.
 FAN Ping,ZHENG Zhuang-hao,LIANG Guang-xing,et al.Preparation of Bi2Te3 thermoelectric thin films by ion beam sputtering[J].Journal of Shenzhen University Science and Engineering,2011,28(2):84.
[3]吕维忠,李金玉,黄旭珊,等.水热法合成PbTe微晶及其微观形貌表征[J].深圳大学学报理工版,2011,28(No.2(095-188)):178.
 LU Wei-zhong,LI Jin-yu,HUAGN Xu-shan,et al.Preparation and morphology characteristics of PbTe microcrystalline synthesized by hydrothermal method[J].Journal of Shenzhen University Science and Engineering,2011,28(2):178.
[4]刘剑洪,吴双泉,何传新,等.碳纳米管和碳微米管的结构、性质及其应用[J].深圳大学学报理工版,2013,30(No.1(001-110)):1.[doi:10.3724/SP.J.1249.2013.01001]
 Liu Jianhong,Wu Shuangquan,He Chuanxin,et al.Structure, property and application of carbon nanotubes and carbon microtubes[J].Journal of Shenzhen University Science and Engineering,2013,30(2):1.[doi:10.3724/SP.J.1249.2013.01001]
[5]唐文伟,陈晓颖,张旻,等.氧化铌掺杂PbO2电极的制备及降解分散蓝B[J].深圳大学学报理工版,2013,30(No.1(001-110)):42.[doi:10.3724/SP.J.1249.2013.01042]
 Tang Wenwei,Chen Xiaoying,Zhang Min,et al.Preparation of Nb2O5 doped PbO2 electrode and its degradation of disperse blue B[J].Journal of Shenzhen University Science and Engineering,2013,30(2):42.[doi:10.3724/SP.J.1249.2013.01042]
[6]李均钦,汪彩艳,逯正旺,等.高性能Ge0.75Pb0.25Te0.5Se0.5固溶体热电材料[J].深圳大学学报理工版,2014,31(3):221.[doi:10.3724/SP.J.1249.2014.03221]
 Li Junqin,Wang Caiyan,Lu Zhengwang,et al.High performance in Ge0.75Pb0.25Te0.5Se0.5 solid solution thermoelectric material[J].Journal of Shenzhen University Science and Engineering,2014,31(2):221.[doi:10.3724/SP.J.1249.2014.03221]

备注/Memo

备注/Memo:
收稿日期:2009-06-15;修回日期:2009-12-16
基金项目:国家自然科学基金资助项目(50471108);广东省科技计划资助项目(2006B14001001)
作者简介:龚晓钟(1960-),女(汉),福建省福州市人,深圳大学教授.E-mail:cici_gxz@163.com
通讯作者:汤皎宁(1961-),男(汉),深圳大学教授.E-mail: tjn@szu.edu.cn
更新日期/Last Update: 2010-05-08